$re = '/(?:^\d+:[^:\r\n]+:$|^:[^:\r\n]+:\d+$|^(?!.*:\b\S+\b:).*$)(*SKIP)(*FAIL)|:[a-z0-9]+:/m';
$str = ':match1::match2: :match3:
:match4:
000:matchNot:
:matchNot:000
:match Not:';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php