$re = '/^((?:(?:(?!")[^|\r\n]*|"[^"\r\n]*"(?=$|\|))(?:$|\|))*+)(")/m';
$str = '123|110092|ACCT|"HC Account"|"Account1||||||||||||"Mary"|||"|"||||132|"STE|504"|1253|Unspecified Account|||N||ACTV|Active||||04/30/2013|12/31/2099|||||||||||||
123|110092|ACCT|"HC Account"|\\"Account1||||||||||||"Mary"|||"|"||||132|"STE|504"|1253|Unspecified Account|||N||ACTV|Active||||04/30/2013|12/31/2099|||||||||||||
123|110092|ACCT|"HC Account"|"Account1||||||||||||"|Mary"|||"|"||||132|"STE|504"|1253|Unspecified Account|||N||ACTV|Active||||04/30/2013|12/31/2099|||||||||||||
123|110092|ACCT|"HC Account"|"Account1||||||||||||"Mary|"|||"|"||||132|"STE|504"|1253|Unspecified Account|||N||ACTV|Active||||04/30/2013|12/31/2099|||||||||||||';
$subst = "$1\\$2";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php