$re = '/^(0+\.[0-9]?e?[+-]?[0-9]+)\s+([0-9]+\.?[0-9]*|[0-9][0-9]?[0-9]?[A-Z][a-z]?)\s+([0-9][0-9]?[0-9]?)\s+(\[.*\])\s+(\[.*\])$/m';
$str = '0.625846 29Si 29 [4934.39 0] [0.84 100000000000000.0]';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php