$re = '/Air.*\s(\-?\d+\.?\d?)C/m';
$str = '24 Jul 2013: Water - 74.0F / 23.3C; Air - 68.0F / 20.0C. John L. helped out a wounded cyclist; Anthony C. swam 1km';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php