$re = '/(\d{2}:\d{2}:\d{2})|([0-9a-z]*.xml)/mi';
$str = 'Time 2014-05-22T10:39:04.890117+01:00 Filename S140522DSS10002.xml::938c287eb522359b600f74bb3140bb64 Generated 2014-05-22T10:38:46.000000+01:00';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php