$re = '/(?:\s*([a-zA-Z()+ ]+?)[ =]*)([-+]?\d+\.?\d*)/m';
$str = 'Molecular weight = 43057.32 Residues = 391
Average Residue Weight = 110.121 Charge = -10.0
Isoelectric Point = 4.8926
Residue Number Mole% DayhoffStat
A = Ala 24 6.138 0.714
B = Asx 0 0.000 0.000
C = Cys 9 2.302 0.794
Property Residues Number Mole%
Tiny (A+C+G+S+T) 135 34.527
Small (A+B+C+D+G+N+P+S+T+V) 222 56.777
Aliphatic (A+I+L+V) 97 24.808';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php