$re = '/^(?:(?!\bNot\b).)*(?=\s+|$)/m';
$str = 'DFE2001 NE Not 1
CAT11004 TP
FFE2001 NE Not 3
AVI2002 NE
LAB4000 SU
BA-PRI008 Not 1
FDD2001 NE Not 2';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php