$re = '/(?<=\s)#\w+(?!.*[@$#])/m';
$str = '1. While #EngineSpeed$b4tgup#
2. While #AcceleratorPedal$desddd# <=2
3. While #AcceleratorPeda@$desddd# <=2
4. While #AcceleratorPe#al$desddd# <=2
5. While #AcceleratorP@dal$desddd# <=2
6. While #AcceleratorPeda l$desddd# <=2
7. 设置 #AcceleratorPedal$y6qs8m#=@AcceleratorPedal+0.06
8. 设置 #WaitStart$jhx0vu#=11
9. 设置 #WaitStart$jhx0vu#^11
10. 设置 #WaitStart$jhx0vu#_11
11. 设置 #WaitStart$jhx0vu#-11
12. 设置 #AcceleratorQuora$yd6ba3#=1
13. 设置 #AcceleratorQuora$yd6bd3#=1
14.
15. Check #EnginePower#
16. While #EngineSpeed
17. set #WaitStart
18. set #WaitStart<13
19. set #WaitStart<=13
20. set #WaitStart <= 13';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php