$re = '/User-Agent: (?<UserAgent>[^\\\\r\\\\n]*)/m';
$str = 'POST /xxx/yyyy HTTP/1.1\\r\\nUser-Agent: Mozilla/5.0 (Windows NT 10.0; Win64; x64; rv:86.0) Gecko/20100101 Firefox/86.0\\r\\nAccept: application/json\\r\\nAccept-Language: en-US,en;q=0.5\\r\\nX-XSRF-TOKEN: 989g8ddfgdf7979df\\r\\ntimestamp: 2021-04-07T18:35:50.639Z\\r\\nContent-Type: application/json;charset=utf-8\\r\\nContent-Length: 340\\r\\nOrigin: https://example.com\\r\\nConnection: keep-alive\\r\\nReferer: https://my.example.com\\r\\n';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php