$re = '/(?s)PROC DATE:\s*(?P<date>\w+)(?:(?!RID:\s+RSS-\d).)*T PUR\s+(?P<num>\d[.,\d]*)\s+(?P<val>\d[\d,]*)/m';
$str = 'RID: RSS-130 SERVICE PAGE: 2
REPORTING FOR: 100019912 SSSE INTSERVICE PROC DATE: 15SEP21
ROLLUP FOR: 100076212 SSSE REPORT REPORT DATE: 15SEP21
ENTITY: 1000208212 SSSE
ACQT
PUR
SAME 10SEP21 120 12,263,518 19,48.5
T PUR 120 12,263,518 19,48.5';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php