$re = '/#[^\s]+|(?<=\s|^)@[^\s@#]+/';
$str = '@twittername blah blah blah #hashtag blah blah @twittername blah email@email.com blah blah #hashtag2 blah blah #h@shtag';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php