$re = '/(?P<Unit_Number>\d*)\s*[\/,\,]\s*(?P<Street_Number>\d*)\s*(?P<Street_Name>[a-zA-Z\s]*),?\s*(?P<State>NSW|ACT|NT|QLD|SA|TAS|VIC|WA)\s*(?P<Post_Code>\d{4})|
(?P<street_number>\d*)\s*(?P<street_name>[a-zA-Z\s]*),?\s*(?P<state>NSW|ACT|NT|QLD|SA|TAS|VIC|WA)\s*(?P<post_code>\d{4})/';
$str = '5/50 street rd suburb, NSW 2000
7 street rd suburb, NSW 2155';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php