$re = '/^(\w+)+\s\|{3}\s(\w+)\s\|{3}\s(.*)/';
$str = 'amornratchatchawansawangwong ||| amornratchatchawansawangwong . ||| 0.594819 0.5 0.594819 0.25 ||| 0-0 0-1 ||| 1 1 1 ||| |||';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php