$re = '/\/item\/(?!page\/).+/m';
$str = 'https://example.com/item/
https://example.com/item/page/2/?wpv_view_count=258
https://example.com/item/page/3/?wpv_view_count=258
https://example.com/item/snv00001-indice-di-documenti/
https://example.com/item/sa00068-libro/
https://example.com/item/aud00068-audio/';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php