$re = '/{\K([A-Z0-9]{8})_([A-Z0-9]{4})_([A-Z0-9]{4})_([A-Z0-9]{4})_([A-Z0-9]{12})(?=})/m';
$str = '{89695C16_C0FF_4E7C_9BB2_8B50FAC9D371}';
$subst = "$1-$2-$3-$4-$5";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php