$re = '/[\w\s\/\.\p{L}\p{N}\p{S}\p{P}]+/';
$str = '/v1/AUTH_sme/stepan/Folders_pack/03 with special characters ~`!@#$%^&()_+-={}[];\',._over_PHP.zzz';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php