$re = '`^DETAIL:.+?\((.+)\).+?\((.+)\) already exists.`m';
$str = 'ERROR: duplicate key value violates unique constraint "uq_content_block_internal_name_store_id"
DETAIL: Key (lower(internal_name::text), store_id)=(some content block-32067683, 0c6d20a7-d843-44f3-af9c-4a2cf2a47e4c) already exists.';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php