re = /(\d+)\.\s"([a-zA-Z ]+)"\s[a-zA-Z \.]+\s([a-zA-Z, \.]+)\s([\d:]+)/m
str = '1. "Anbae Anbae" Vairamuthu Hariharan, K. S. Chitra 5:10
2. "I Love You" Vairamuthu Nandini Srikar, KK, Ajith Kumar 4:55
3. "Nathi Enge Valaiyum" Vairamuthu Ghanshyam Vaswani 4:37
4. "Nothing Nothing" Vairamuthu Harini 4:44
5. "Poovukellam Siragu" Vairamuthu Srinivas, KK, Harini 5:27
6. "Vannakili SolKonda" Vairamuthu Gopal Rao, Harini, Chorus 4:38'
subst = '\\1 \\2 - \\3 \\4'
result = str.gsub(re, subst)
# Print the result of the substitution
puts result
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for Ruby, please visit: http://ruby-doc.org/core-2.2.0/Regexp.html