$re = '/([^?=&]+)(=([^&]*))?/m';
$str = 'Signature Algorithm=ecdsa-with-SHA256&Not Before=Jul 23 00:00:002018 GMT&Not After=Jul 19 00:00:00 2033 GMT';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php