$re = '/(?![\u2764])[\U00010000-\U0010ffff]/mu';
$str = 'This book is so funny❤️. This book 📖 is the bomb(AS IN THE BEST
IN THE WORLD 🌎 🌍🗺 )I love 💗 💕 💖 it!I definitely recommend it!';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php