$re = '/^(?<tipo_de_registro>\d)(?<codigo_de_retorno>\d)(?<literal_de_retorno>.{7})(?<codigo_de_servico>\d{2})(?<literal_de_servico>.{15})(?<agencia>\d{4})(?:\d{2})(?<conta>\d{5})(?<dac>\d{1})(?:.{8})(?<nome_da_empresa>.{30})(?<codigo_do_banco>\d{3})(?<nome_do_banco>.{15})(?<data_de_geracao>\d{6})(?<desidade>\d{5})(?<unidade_de_desidade>.{3})(?<numero_sequencial_arq_retorno>\d{5})(?<data_de_credito>\d{6})(?:.{275})(?<numero_sequencial>\d{6})/m';
$str = '02RETORNO01COBRANCA 063700710369 MINASMAQUINAS ADM CONS LTDA 341BANCO ITAU S.A.26052101600BPI03305270521 000001maynewayent.com ';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php