$re = '/\b(a_msg)\b[^\"]+\"(?<a_msg>[^\"]*)\"/m';
$str = '{"log":"a_level=\\"INFO\\", a_time=\\"2021-09-17 07:33:35,210\\", a_msg=\\"CommissionRouteType: Client / clientId: 111/ planId: 111 / PolicyBusinessId: 111\\","level":"info"}';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php