$re = '/\.(\w*)$/';
$str = 'http://www.style-for-u.com/wp-content/uploads/2014/08/T-shirt-femme-imprim%C3%A9-voilier-Petit-Bateau-env-50%E2%82%AC.jpg';
$subst = "-150x150.$1";
$result = preg_replace($re, $subst, $str, 1);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php