$re = '/(?<a1>\d{10})_(?<a2>\d{10})_(?<a3>\D{4})_(?<a4>\d{2}).(?<a5>\d{2}).(?<a6>\d{4})_(?<a7>\D{2})_(?<a8>\d{2}).(?<a9>\d{2}).(?<a10>\d{4})_(?<a11>\d{3})_(?<a12>\d+).(?<a13>\D{3})/';
$str = '2016000009_0002583207_From_04.01.2016_To_04.01.2016_001_1.PDF';
preg_match($re, $str, $matches, PREG_OFFSET_CAPTURE, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php