$re = '/(<!-- s(\S*) --><img src="\S*" alt="\S*" title="[^"]+" \/><!-- s\S* -->)/';
$str = '<!-- s:D --><img src="{SMILIES_PATH}/icon_biggrin.gif" alt=":D" title="Very Happy" /><!-- s:D --> <!-- scat --><img src="{SMILIES_PATH}/cat2.gif" alt="cat" title="Cat" /><!-- scat -->';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php