$re = '/(?=(?:(?:[^"][do_collapse"){2})*[^"]*$)))/';
$str = '[do_collapse id=\'dsds\'] fewfw fewfw [/do_collapse] @user1 @user2 ignoreme
[header]frfw[/header]
:\\)(?=(?:(?:[^"][do_collapse"){2})*[^"]*$)';
preg_match($re, $str, $matches, PREG_OFFSET_CAPTURE, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php