$re = '/,(?=[^\]]*(?:\[|$))(?=[^}]*(?:{|$))/';
$str = 'RR,target_value,006EI4ZXZALFXAT2E4AHX2O6V,006EI4ZXZALFXAT2E4AHX2O6V,dynamic,{\\"(MEASURES_DIMENSION)\\":\\"006EI4ZXZALFXAT2E4AHX2O6V\\",\\"ZR_ITEM__ZR_BRAND\\":\\"0000000201\\"},cell_selection,34932,#FFFFFF,,25,[{\\"color\\":\\"#566C6C\\",\\"from\\":\\"10\\",\\"to\\":\\"50\\",\\"icon\\":\\"fa://minus-with-square\\",\\"size\\":\\"30\\",\\"angle\\":\\"45\\"}]';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php