$re = '/<Row>w+/';
$str = ' <Row>
<INVOICE_NUMBER>NULL</INVOICE_NUMBER>
<KOD_MATER>232820</KOD_MATER>
<KOD_EAN>4620008991313</KOD_EAN>
<SERIA>100</SERIA>
<D_BEGIN>224515001</D_BEGIN>
<D_END>224520000</D_END>
<EGAIS>0150117000001837067</EGAIS>
<N_ZAYAV>82</N_ZAYAV>
<N_GTD>NULL</N_GTD>
<MANUFACTURE>5029047184</MANUFACTURE>
<DATE_BOTTLING>24.07.2014</DATE_BOTTLING>
</Row>
<Row>
<INVOICE_NUMBER>NULL</INVOICE_NUMBER>
<KOD_MATER>232820</KOD_MATER>
<KOD_EAN>4620008991313</KOD_EAN>
<SERIA>100</SERIA>
<D_BEGIN>224520001</D_BEGIN>
<D_END>224525000</D_END>
<EGAIS>0150117000001837067</EGAIS>
<N_ZAYAV>82</N_ZAYAV>
<N_GTD>NULL</N_GTD>
<MANUFACTURE>5029047184</MANUFACTURE>
<DATE_BOTTLING>24.07.2014</DATE_BOTTLING>
</Row>';
preg_match($re, $str, $matches, PREG_OFFSET_CAPTURE, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php