$re = '/<a(?=[^>]*?rel=nofollow)(?=[^>]*?href="http:\/\/www\.mysite\.com\/.*?")[^>]*?>/';
$str = '<a .rel=nofollow .. href="http://www.mysite.com/xyz...." ... >
<a . .. href="huntoffice.ie" ..rel=nofollow. >
<a...> rel=nofollow href="http://www.mysite.com/"';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php