$re = '/\bcat(?!12\b)\d+/m';
$str = 'cat3 YES
cat12 NO
cat43 YES
cat18 YES
rel97 NO
cat NO
cat36 YES
cat14 YES
cat121
cat123
cat13
cat10
cat11
cat13
cat100
cat10099
cat130
cat120';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php