$re = '/(<VirtualHost\s\*:9007>[\s\S]*?[^#]\s<Directory\s)[\/._a-z]+(>[\s\S]*?<\/VirtualHost>)/';
$str = '<VirtualHost *:80>
ScriptAlias /cgi-bin /var/www/cgi-bin
ServerName lp.kyivstar.net
DocumentRoot /var/www/kyivstar.net/public_html
<Directory /var/www/kyivstar.net/>
Options +ExecCGI -Indexes
AllowOverride All
Order allow,deny
Allow from all
SetHandler application/x-httpd-php-7.4.0
</Directory>
ErrorLog ${APACHE_LOG_DIR}/error.log
CustomLog ${APACHE_LOG_DIR}/access.log combined
</VirtualHost>
<VirtualHost *:9007>
ScriptAlias /cgi-bin /var/www/cgi-bin
DocumentRoot /var/www/test.loc/public_html
#<Directory /var/www/test2.loc/>
<Directory /var/www/test.loc/>
Options +ExecCGI -Indexes
AllowOverride All
Order allow,deny
Allow from all
SetHandler application/x-httpd-php-7.3.6
</Directory>
ErrorLog ${APACHE_LOG_DIR}/error.log
CustomLog ${APACHE_LOG_DIR}/access.log combined
</VirtualHost>
<VirtualHost *:443>
</VirtualHost>';
preg_match($re, $str, $matches, PREG_OFFSET_CAPTURE, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php