$re = '/^[^\W_](?:[\w.-]*[^\W_])?@(?:\[[0-9]{1,3}\.[0-9]{1,3}\.[0-9]{1,3}\.|(?:[\w-]+\.)+)(?:[a-zA-Z]{2,3}|[0-9]{1,3})\]?$/m';
$str = 'abc@site.com
.abc@site.com
_abc@site.com
9abc@site.com
9abc.@site.com
a@site.com
!@site.com
a!@site.com';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php