$re = '/((?:\d\d;){2}\d+)/';
$str = '***01;01;283***;Póvoa do Vâle do Trigo;15315100 ***01;01;249***;Alcafaz;;;;;;;;;;;3750;011;AGADÃO ***01;01;2504***;Caselho;;;;;;;;;;;3750;012;AGADÃO _ "15" \'\' ghdhghg **AND IT CONTINUES**
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php