$re = '/.(?=..\.TIF$)/m';
$str = 'VK1006_00_0010 00PLATE BEND 039333 0101116201 DE1 D 1.TIF
NB1022_01_5210 03PANHARD ROD 062193 010111- DH8 C01.TIF
TB1072_02_PLATE 01OOOOOD 89173001001 DC1.TIF
VA1056_01_1050 02TUBES 080129 010111- DA1 A01.TIF';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php