$re = '/<h1>(.*?)<\/h1>((?!<h1>))*/m';
$str = '<h1>Foo</h1><h2>Bar</h2><h1>Baz</h1><h3>Test</h3><h1>ghj</h1>zuio';
$subst = "$1 $2";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php