$re = '/"value2":\s*\K[^\s,]*(?=\s*,)/m';
$str = '{"value1":5.0,"value2":2.5,"value3":"2019-10-24T15:26:00.000Z","modifier":[]}
{"value1": 5.0,
"value2": 2.5,
"value3": "2019-10-24T15:26:00.000Z",
"modifier":[]}';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php