$re = '/(?<first>\d)(\k<first>)\d?(?<second>(?!\k<first>)\d)(\k<second>)/';
$str = '12345
11223
44433
15151
22551
22055
22022
11111
11122
11222
12526';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php