$re = '/^(from|to|cc|bcc):.*(?:\R(?!(?:(?1)|$)).*)*/m';
$str = 'From support@test.co.uk Wed Nov 20 15:48:00 2013
Return-Path: <support@test.co.uk>
X-Original-To: mailbox@my.domain.com
Delivered-To: mailbox@my.domain.com
Delivered-To: techinfo@test.co.uk
from: "Lucy 1" <support@lucky1.co.uk>,"Lucy 2" <support@lucky2.co.uk>,
"Lucy 3" <support@lucky3.co.uk>
to: TestTo <techinfo@test.co.uk>
testestest
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php