$re = '/(?:((?<=[\s\W])|^)[#](\w+|[^#]|$)|((?<=[\s\W])|^)[@]([a-zA-Z0-9_]+|$))/m';
$str = 'This week, four astronauts arrived at @NASAKennedy for NASA\'s
@SpaceX Crew-1 launch to the @Space_Station. Their six-month mission will be filled with @ISS_Research, from technology demonstrations to space gardening. More on #SpaceToGround: http://youtu.be/bBKe3cuw-b8';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php