$re = '/(?<First>\w+?) (?# First word UNGREEDY)
(?> (?# Second group - see it is optional)
(?>_) (?# But if it exists, must start with "_" NON CAPTURING GROUP )
(?<Second>\w+) (?# Snd then there should be a word - at least one char)
)* (?# remember - the group is optional)
\b (?# All the puttern must finish with word boundary)/mx';
$str = ' BRIGHTER
DIMMER
CYCLE_RGB
CYCLE_ALL
PULSE_WHITE
SMOOTH
';
$subst = "\U${FirstUpper}\L${FollowingUppers}\U${SecondUpper}\L${FollowingUppers2} = ${HexCode},";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php