$re = '/(\d{0,2}:\d{2}(?:\.\d+)?)/';
$str = '"R uses 1:5 for 1, 2, 3, 4, 5.",
"At 3:00 we\'ll meet up and leave by 4:30:20.",
"We\'ll meet at 6:33.", "He ran it in :22.34."
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php