$re = '/\s* \s*/m';
$str = '18:30
18:20
17:30
18:30
17:58
18:00
19:00 18:41
18:00
19:00
18:12 19:00 21:00
20:11 20:00 21:00
20:56
21:00 22:00 21:33';
$subst = "$0\n";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php