$re = '/<li.*?id=".*?([\d]+)".*?<a.*?>.*?([\w]+)<\/a>/';
$str = '<li id="ncc-nba-16451" class="che10"><a href="/en/star">23 - Star</a></li>
<li id="ncd-bbt-5674" class="che10"><a href="/en/moon">54 - Moon</a></li>
<li id="ertw-cxda-c6543" class="che10"><a href="/en/sun">34,780 - Sun</a></li>';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php