$re = '/(Playing|Listening).*?\(\{2\}\)\0(([^\\\\0].).)$/';
$str = '\\0Music\\01\\0Playing {0} - {1} [{3}] ({2})\\0With You Tonight\\0viewtifulday\\0osu!\\0Normal\\0';
$subst = "\U$1";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php