$re = '/\b(?!\s)([A-Z\sÀÈÌÒÙÁÉÍÓÚÝÂÊÎÔÛÃÑÕÄËÏÖÜŸ]{4,})\b[^A-ZÀÈÌÒÙÁÉÍÓÚÝÂÊÎÔÛÃÑÕÄËÏÖÜŸ]*CPF.*?(\d{3}.\d{3}.\d{3}.\d{2})/m';
$str = 'NOT THIS NAME, blah blah, ETC ETC ETC, XXXX 00.000.000/0001-00, blah blah, 123, ZIP 12345-123, blah blah, blah TEXT TEXT TEXT TEXT, blah blah THIS NAME, blah blah, blah blah CPF 999.999.999-99 blah blah';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php