$re = '/\d*([ A-Z]+((SL[1-9])?[ ]?[0-9A-Z]+)?,)+/i';
$str = '14 College Rd, Maidenhead, Windsor and Maidenhead SL6 6BN, UK';
preg_match($re, $str, $matches, PREG_OFFSET_CAPTURE, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php