$re = '/(?m)^([0-9]{1,2}\.[0-9]{1,2}\.[0-9]{4}\s*)(05:00)(?=.*\s+^\1\2)/';
$str = '31.03.2024 01:00 1.002
31.03.2024 03:00 2.003
31.03.2024 05:00 3.007
31.03.2024 05:00 4.985
31.03.2024 06:00 2.987';
$subst = "${1}04:00";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php