$re = '/^((?:\d+\.?){4})(?:.+?"){4}\s+(".*?")/m';
$str = '66.249.74.18 - - [21/Apr/2013:05:55:33 +0000] 200 "GET /1.jpg HTTP/1.1" 7691 "-" "Googlebot-Image/1.0" "-"
220.181.108.96 - - [21/Apr/2013:05:55:33 +0000] 200 "GET /1.html HTTP/1.1" 17722 "-" "Mozilla/5.0 (compatible; Baiduspider/2.0; +http://www.baidu.com/search/spider.html)" "-"';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php