$re = '/^(?!(.*?\|[А-Я][а-я]{2,}\|[А-Я][а-я]{2,}\|))/m';
$str = 'email1@pochta.ru|Имя|Фамилия|2|1965-10-06|
email2@pochta.ru|дебильное имя|дебилЬная ФамилиZ|2|1976-04-03|Россия, Московская обл.';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php