$re = '/\s+\\\\\[\s*(?P<brace_bloc>.*?)\s*\\\\\]\s+/ms';
$str = 'foo \\[ \\left\\\\{
\\begin{array}{cl}3=&1 + 2\\\\4=&2 + 2\\end{array}
\\right.
\\]
bar';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php